At Mater Dei Catholic Primary School Blakehurst, all staff work collaboratively within their roles to achieve the best possible outcomes for our community.
| Principal | Melanie Headley |
| Assistant Principal | Brad Cummins |
| R.E. Coordinator | Sarah Barr |
| Coordinator 1 | Katie Penman |
| Coordinator 1 | Michele Belarra |
| Coordinator 1 | Allira Lucchitti |
| Coordinator 1 | Rylee Walsh |
| Learning Support Officers | Annette Simeon |
| Learning Support Officers | Alison Gibbons |
| Learning Support Officers | Karen Zinnato |
| Learning Support Officers | Christine Moy |
| Learning Support Officers | Rebecca Prachanh |
| Learning Support Officers | Cassie Nielsen |
| Learning Support Officers | Shelley Alexander |
| Learning Support Officers | Dayna Burgess |
| Office and Administration | Susan Benhiam-Cusack |
| Office and Administration | Brigitta Robinson |
| Office and Administration | Karen Zinnato |
| ISO | Enoch To |
| Kindergarten | Brooke Baxter |
| Kindergarten | Julia Vournazos |
| Year 1 | Allira Lucchitti |
| Year 1 | Audrian Aldana |
| Year 2 | Lisa Sebelic & James Livirizzi |
| Year 2 | Sarah Maguire |
| Year 3 | Faye Reardon |
| Year 3 | Nadia Bertah |
| Year 4 | Julie Marshall |
| Year 4 | Rylee Walsh |
| Year 5 | Bianca Zagame |
| Year 5 | Sophie Smith |
| Year 6 | Annie Niulala |
| Year 6 | Brad Cummins & James Livirizzi |
| Diverse Learning | Shelley Watts |
| EAL/D | Julie Marshall & Kathy Smith |
| Reading Recovery | Melanie Southall |
| Music/Dance/Drama | Sarah Barr |
| Sport | Sue Ambrose |
| Library | Gae Flood |
| Family Educator | Sonia Reilly |